Charles A. Mebi
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Professor of Chemistry
Also affiliated: University of Nevada, Reno (2004–2019); University of Arizona (2008–2013)
Formerly Arkansas Associate Professor of Chemistry, Arkansas Tech University through 2017; now Professor of Chemistry, Arkansas Tech University.
Research Areas
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Biography and Research Information
OverviewAI-generated summary
Charles A. Mebi's research focuses on organometallic chemistry, particularly the synthesis, structure, and reactivity of metal complexes. His work has investigated complexes containing the Fe2S2 core, which are characteristic of [FeFe]-hydrogenases, and their role in catalyzing the reduction of acids to form dihydrogen. Mebi has also explored the pH-dependent selective transfer hydrogenation of α,β-unsaturated carbonyls using half-sandwich ruthenium(II) complexes and the aqueous organometallic chemistry of water-soluble metal hydrides.
His research interests extend to the synthesis and coordination chemistry of novel phosphine ligands, such as 6-(diphenylphosphino)-1,3,5-triaza-7-phosphaadamantane (PTA-PPh2), and the study of boron–nitrogen adducts of 1,3,5-triaza-7-phosphaadamantane (PTA). Mebi has also employed density functional theory (DFT) to study the structure, electronic properties, and reactivity of specific cis-isomers of metal complexes. His scholarly contributions include 70 publications, with an h-index of 16 and over 1,200 citations.
Metrics
- h-index: 16
- Publications: 70
- Citations: 1,279
Positions
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Professor of Chemistry publications 2010–2020Arkansas Tech University Institution web page
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Associate Professor of Chemistry 2015–2017Arkansas Tech University Department of Physical Sciences ORCID
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Assistant Professor of Chemistry 2009–2015Arkansas Tech University Department of Physical Sciences ORCID
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Postdoctoral Research Associate 2007–2009University of Arizona Chemistry and Biochemistry ORCID
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Adjunct Faculty 2007–2008Pima Community College Science ORCID
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Graduate Teaching and Research Assistant 2002–2007University of Nevada Reno Chemistry ORCID
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Assistant Lecturer 2000–2002University of Buea Chemistry ORCID
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Instructor 1999–2000University of Buea Chemistry ORCID
Selected Publications
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Macrocyclic tetranuclear double-butterfly Fe/S carbonyl clusters as [FeFe]-hydrogenase models (2020)
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Synthesis, crystal structure, and thermal behavior of a diiron toluenethiolate complex with triphenylphosphine coligand (2020)
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Metalloenzyme mimic: diironhexacarbonyl cluster coupled to redox-active 4-mercapto-1,8-naphthalic anhydride ligands (2020)
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Cyclic tetranuclear iron-carbonyl complex containing thiobisbenzenethiolate ligands: Synthesis and structural characterization (2018)
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Crystal and electronic structure of a hexacarbonyldiiron cluster tethered to naphthalene-2-thiolate ligands (2018)
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Phenylthiolate-diironhexacarbonyl complexes: a comparative conceptual DFT and electrochemical study (2016)
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[Fe–Fe] hydrogenase models: Iron(I)-carbonyl clusters coupled to alpha- and para-toluenethiolate ligands (2015)
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Biomimetic hydrogen generation catalyzed by triironnonacarbonyl disulfide cluster (2012)
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Diironcarbonyl-coumarin complex: preparation, intramolecular electron transfer, and electro-generation of hydrogen (2012)
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Using naphthalene-2-thiolate ligands in the design of hydrogenase models with mild proton reduction overpotentials (2012)
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Iron(I)-carbonyl clusters tethered to (trifluoromethyl)thiophenolates (2012)
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DFT study on structure, electronic properties, and reactivity of cis-isomers of [(NC5H4-S)2Fe(CO)2] (2011)
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Diironhexacarbonyl clusters with imide and amine ligands: hydrogen evolution catalysts (2011)
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Iron Carbonyl Cluster linked to Naphthalenedithiolates (2010)
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Binuclear Iron(I) Complex Containing Bridging Phenanthrene‐4,5‐dithiolate Ligand: Preparation, Spectroscopy, Crystal Structure, and Electrochemistry (2010)
Collaboration Network
Top Collaborators
- [Fe–Fe] hydrogenase models: Iron(I)-carbonyl clusters coupled to alpha- and para-toluenethiolate ligands
- Cyclic tetranuclear iron-carbonyl complex containing thiobisbenzenethiolate ligands: Synthesis and structural characterization
- Synthesis, crystal structure, and thermal behavior of a diiron toluenethiolate complex with triphenylphosphine coligand
- Crystal and electronic structure of a hexacarbonyldiiron cluster tethered to naphthalene-2-thiolate ligands
- Macrocyclic tetranuclear double-butterfly Fe/S carbonyl clusters as [FeFe]-hydrogenase models
- Using naphthalene-2-thiolate ligands in the design of hydrogenase models with mild proton reduction overpotentials
- Binuclear Iron(I) Complex Containing Bridging Phenanthrene‐4,5‐dithiolate Ligand: Preparation, Spectroscopy, Crystal Structure, and Electrochemistry
- Iron(I)-carbonyl clusters tethered to (trifluoromethyl)thiophenolates
- Using naphthalene-2-thiolate ligands in the design of hydrogenase models with mild proton reduction overpotentials
- Diironhexacarbonyl clusters with imide and amine ligands: hydrogen evolution catalysts
- Binuclear Iron(I) Complex Containing Bridging Phenanthrene‐4,5‐dithiolate Ligand: Preparation, Spectroscopy, Crystal Structure, and Electrochemistry
- Iron(I)-carbonyl clusters tethered to (trifluoromethyl)thiophenolates
- Diironcarbonyl-coumarin complex: preparation, intramolecular electron transfer, and electro-generation of hydrogen
- Iron(I)-carbonyl clusters tethered to (trifluoromethyl)thiophenolates
- Biomimetic hydrogen generation catalyzed by triironnonacarbonyl disulfide cluster
- Diironhexacarbonyl clusters with imide and amine ligands: hydrogen evolution catalysts
- Binuclear Iron(I) Complex Containing Bridging Phenanthrene‐4,5‐dithiolate Ligand: Preparation, Spectroscopy, Crystal Structure, and Electrochemistry
- Metalloenzyme mimic: diironhexacarbonyl cluster coupled to redox-active 4-mercapto-1,8-naphthalic anhydride ligands
- Crystal and electronic structure of a hexacarbonyldiiron cluster tethered to naphthalene-2-thiolate ligands
- Iron(I)-carbonyl clusters tethered to (trifluoromethyl)thiophenolates
- Iron(I)-carbonyl clusters tethered to (trifluoromethyl)thiophenolates
- Diironcarbonyl-coumarin complex: preparation, intramolecular electron transfer, and electro-generation of hydrogen
- Biomimetic hydrogen generation catalyzed by triironnonacarbonyl disulfide cluster
- [Fe–Fe] hydrogenase models: Iron(I)-carbonyl clusters coupled to alpha- and para-toluenethiolate ligands
- [Fe–Fe] hydrogenase models: Iron(I)-carbonyl clusters coupled to alpha- and para-toluenethiolate ligands
- [Fe–Fe] hydrogenase models: Iron(I)-carbonyl clusters coupled to alpha- and para-toluenethiolate ligands
- [Fe–Fe] hydrogenase models: Iron(I)-carbonyl clusters coupled to alpha- and para-toluenethiolate ligands
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